Radical annulation methodology. 2-Vinylcyclopentane derivative formation by a 3 + 2 cycloaddition reaction
نویسندگان
چکیده
منابع مشابه
Reaction of alpha-ene-vinylcyclopropanes: type II intramolecular [5+2] cycloaddition or [3+2] cycloaddition?
Exposure of alpha-ene-VCPs to catalytic [Rh(dppm)]SbF(6) led to the discovery of a novel Rh(I)-catalyzed [3+2] reaction, which was shown to be efficient for the construction of 5/6- and 5/7-bicyclic compounds rather than the anticipated type II [5+2] products.
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ژورنال
عنوان ژورنال: Tetrahedron Letters
سال: 1990
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)97582-8